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In future decarbonized scenarios, hydrogen is widely considered as one of the best alternative fuels for internal combustion engines, allowing to achieve zero CO2 emissions at the tailpipe. However, NOx emissions represent the predominant pollutants and their production has to be controlled. In this work different strategies for the control and abatement of pollutant emissions on a H2-fueled high-performance V8 twin turbo 3.9L IC engine are tested. The characterization of pollutant production on a single-cylinder configuration is carried out by means of the 1D code Gasdyn, considering lean and homogeneous conditions. The NOx are extremely low in lean conditions with respect to the emissions legislation limits, while the maximum mass flow rate remains below the turbocharger technical constraint limit at λ=1 only.

Remote emission sensing (RES) is a non-intrusive measurement method based on absorption spectroscopy, which allows for the determination of pollutant concentrations in vehicle exhaust plumes. By measuring the absorption of the exhaust plume from the roadside using a light/laser barrier, concentration ratios of pollutants, such as nitrogen oxides to carbon dioxide, can be estimated. Computational fluid dynamics (CFD) has been employed to simulate vehicle exhaust plumes due to uncertainties in RES capabilities. In a previous study, Unsteady Reynolds-Averaged Navier-Stokes (URANS) simulations were conducted to investigate the dispersion of vehicle exhaust plumes under various ambient/driving conditions and provide insights for RES applications. However, the accuracy of these simulations can be further improved. Therefore, this study focuses on enhancing the simulation accuracy by employing large eddy simulations (LES).

NH₃/urea SCR is a very effective and widely used technology for the abatement of NOx from diesel exhaust. The SCR mechanism is well understood and the catalyst behavior can be predicted by mathematical models - as long as operation above the temperature limit for AdBlue® injection is considered. The behavior below this level is less understood. During the first seconds up to minutes after cold start, complete NOx abatement can be observed over an SCR catalyst in test bench experiments, together with a significant increase in temperature after the converter (ca. 100 K). In this work these effects have been investigated over a monolith Cu-zeolite SCR catalyst. Concentration step experiments varying NO, NO₂ and H₂O have been carried out in lab scale, starting from room temperature. Further, the interaction of C₃H₆ and CO with NOx over the SCR has been investigated.

Predictive combustion models are useful tools towards the development of clean and efficient engines operating with alternative fuels. This work intends to validate two different combustion models on compression-ignition engines fueled with Dimethyl Ether. Both approaches give a detailed characterization of the combustion kinetics, but they substantially differ in how the interaction between fluid-dynamics and chemistry is treated. The first one is single-flamelet Representative Interactive Flamelet, which considers turbulence-kinetic interaction but cannot correctly describe the stabilization of the flame. The second, named Tabulated Well Mixed, correctly accounts for local flow and mixture conditions but does not consider interaction between turbulence and chemistry. An experimental campaign was carried out on a heavy-duty truck engine running on DME at a constant load considering trade-off of EGR and SOI.

The abatement of carbon dioxide and pollutant emissions on motorbike spark-ignition (SI) engines is a challenging task, considering the small size, the low cost and the high power-to-weight ratio required by the market for such powertrain. In this context, the passive pre-chamber (PPC) technology is an attractive solution. The combustion duration can be reduced by igniting the air-fuel mixture inside a small volume connected to the cylinder, unfolding the way to high engine efficiencies without penalization of the peak performance. Moreover, no injectors are needed inside the PPC, guaranteeing a cheap and fast retrofitting of the existing fleet. In this work, a 3D computational fluid dynamics (CFD) investigation is carried out over an experimental configuration of motorbike SI engine, operated at fixed operating conditions with both traditional and PPC configurations.

Air pollution is a significant environmental issue, and exhaust emissions from internal combustion engines are one of the primary sources of harmful pollutants. The transportation sector, which includes road vehicles, contributes to a large share of these emissions. In Europe, the latest emission legislation (Euro 7) proposes more stringent limits and testing conditions for vehicle emissions. To meet these limits, the automotive industry is actively developing innovative exhaust emission-control technologies. With the growing prevalence of electrification, internal combustion engines are subject to continuous variations in load and engine speed, including phases where the engine is switched off. The result is an operating condition characterized by successive cold starts. In this context, the challenge in coping with the emission limits is to minimize the light-off time and prevent fast light-out conditions during idling or city driving.